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NEET CHEMISTRYMedium

In a zero-order reaction for every 10 °C rise of temperature, the rate is doubled. If the temperature is increased from 10 °C to 100 °C, the rate of the reaction will become:

A

256 times

B

512 times

C

64 times

D

128 times

Step-by-Step Solution

The effect of temperature on the rate of reaction is often described by the temperature coefficient. It is a general observation (often cited as a rule of thumb in NCERT) that for a chemical reaction, with a rise in temperature by 10°, the rate constant (and thus the rate) is nearly doubled .

To calculate the final rate increase, we use the formula: Rate2Rate1=(Temperature Coefficient)ΔT10\frac{\text{Rate}_2}{\text{Rate}_1} = (\text{Temperature Coefficient})^{\frac{\Delta T}{10}}

Given: Temperature Coefficient = 2 (rate doubles) Initial Temperature (T1T_1) = 10 °C Final Temperature (T2T_2) = 100 °C ΔT=100C10C=90C\Delta T = 100^\circ\text{C} - 10^\circ\text{C} = 90^\circ\text{C}

Calculation: Factor=2(90/10)=29\text{Factor} = 2^{(90/10)} = 2^9 29=5122^9 = 512

Thus, the rate of the reaction becomes 512 times the initial rate.

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