In ion, the number of bond pair and lone pair of electrons on nitrogen atom are respectively:
2 and 2
3 and 1
1 and 3
4 and 0
To determine the number of bond pairs and lone pairs on the nitrogen atom in the nitrate ion (), we apply the principles of Lewis structures and covalency. Nitrogen is a second-period element with five valence electrons . In , the total number of valence electrons is 24 (5 from , 18 from three atoms, and 1 from the negative charge). The nitrogen atom acts as the central atom and forms four bonds—one double bond and two single bonds—to complete the octets of the surrounding oxygen atoms . This results in 4 bond pairs shared by the nitrogen atom. Because the maximum covalency of nitrogen is 4 and it cannot expand its octet due to the absence of d-orbitals, all available bonding capacity is used, leaving 0 lone pairs on the nitrogen atom .
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