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Product 'P' in the following reaction is: RMgX+CO2dry\etherYH3O+PR-Mg-X + CO_2 \xrightarrow{dry\ether} Y \xrightarrow{H_3O^+} P

A

RCHO

B

RCOOH

C

RCH2OH

D

RCOOR'

Step-by-Step Solution

The reaction of a Grignard reagent (RMgXR-Mg-X) with carbon dioxide (CO2CO_2) is a standard method for the preparation of carboxylic acids.

  1. Nucleophilic Attack: The alkyl group (RR^-) of the Grignard reagent acts as a nucleophile and attacks the electrophilic carbon of CO2CO_2 (O=C=OO=C=O).
  2. Intermediate: This forms an addition product, a salt of the carboxylic acid (RCOOMg+XR-COO^-Mg^+X).
  3. Hydrolysis: Upon acidification (hydrolysis with H3O+H_3O^+), the salt is converted into the corresponding carboxylic acid (RCOOHRCOOH).

RMgX+O=C=ORC(OMgX)=OH3O+RCOOHR-Mg-X + O=C=O \rightarrow R-C(OMgX)=O \xrightarrow{H_3O^+} R-COOH

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