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NEET CHEMISTRYMedium

The correct order of 1st IP (ionization potential) among the following elements Be, B, C, N, O is:

A

B < Be < C < O < N

B

B < Be < C < N < O

C

Be < B < C < N < O

D

Be < B < C < O < N

Step-by-Step Solution

Generally, ionization enthalpy increases across a period from left to right. However, there are two important anomalies in the second period involving the elements given:

  1. Boron (B) vs. Beryllium (Be): Beryllium (Z=4Z=4) has a stable, fully filled 2s2s subshell (1s22s21s^2 2s^2). Boron (Z=5Z=5) has the configuration 1s22s22p11s^2 2s^2 2p^1. The 2s2s electron penetrates closer to the nucleus than the 2p2p electron and is more strongly attracted. Therefore, it is easier to remove the 2p2p electron from Boron than the 2s2s electron from Beryllium. Thus, IE1(B)<IE1(Be)IE_1(B) < IE_1(Be).
  2. Oxygen (O) vs. Nitrogen (N): Nitrogen (Z=7Z=7) has a stable, half-filled 2p2p subshell (1s22s22p31s^2 2s^2 2p^3). Oxygen (Z=8Z=8) has the configuration 1s22s22p41s^2 2s^2 2p^4. The repulsion between the two electrons occupying the same 2p2p orbital in oxygen makes it easier to remove one electron compared to the stable half-filled configuration of nitrogen. Thus, IE1(O)<IE1(N)IE_1(O) < IE_1(N).

Combining these trends with the general increase across the period, the correct order is: B < Be < C < O < N.

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