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NEET CHEMISTRYMedium

Gadolinium belongs to 4f series. It’s atomic number is 6464. Which of the following is the correct electronic configuration of gadolinium?

A

[Xe]4f86d2[\text{Xe}] 4f^8 6d^2

B

[Xe]4f95s1[\text{Xe}] 4f^9 5s^1

C

[Xe]4f75d16s2[\text{Xe}] 4f^7 5d^1 6s^2

D

[Xe]4f65d26s2[\text{Xe}] 4f^6 5d^2 6s^2

Step-by-Step Solution

Gadolinium (Gd) has an atomic number of 6464. The nearest noble gas is Xenon (Xe\text{Xe}, Z=54Z = 54). The remaining 1010 electrons are to be filled in the 4f4f, 5d5d, and 6s6s orbitals. The general electronic configuration of lanthanoids is [Xe]4f1145d016s2[\text{Xe}] 4f^{1-14} 5d^{0-1} 6s^2. To acquire the extra stability associated with a half-filled ff-subshell (4f74f^7), one electron enters the 5d5d orbital instead of pairing up in the 4f4f orbital. Therefore, the ground state electronic configuration of Gadolinium is [Xe]4f75d16s2[\text{Xe}] 4f^7 5d^1 6s^2.

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