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NEET CHEMISTRYMedium

The number of unpaired electrons in the complex ion [CoF6]3[CoF_6]^{3-} is: (Atomic No. Co = 27)

A

2

B

3

C

4

D

Zero

Step-by-Step Solution

In the complex ion [CoF6]3[CoF_6]^{3-}, the central cobalt atom is in the +3+3 oxidation state. The ground state electronic configuration of Co (Z = 27) is [Ar]3d74s2[Ar] 3d^7 4s^2, so Co3+Co^{3+} has a 3d63d^6 configuration. Fluoride (FF^-) is a weak field ligand, so it does not cause forced pairing of the inner 3d3d electrons. The complex uses outer 4d4d orbitals and undergoes sp3d2sp^3d^2 hybridization, forming a high-spin (outer orbital) complex. According to Hund's rule, the six 3d3d electrons are arranged to give the maximum number of unpaired electrons (configuration t2g4eg2t_{2g}^4 e_g^2 in CFT). Therefore, there are 4 unpaired electrons.

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