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NEET CHEMISTRYEasy

The equilibrium constant KpK_p for the following reaction is: MgCO3(s)MgO(s)+CO2(g)\text{MgCO}_3(s) \rightleftharpoons \text{MgO}(s) + \text{CO}_2(g)

A

Kp=PCO2K_p = P_{\text{CO}_2}

B

Kp=PCO2×PMgOPMgCO3K_p = \frac{P_{\text{CO}_2} \times P_{\text{MgO}}}{P_{\text{MgCO}_3}}

C

Kp=PCO2+PMgOPMgCO3K_p = \frac{P_{\text{CO}_2} + P_{\text{MgO}}}{P_{\text{MgCO}_3}}

D

Kp=PMgCO3PCO2×PMgOK_p = \frac{P_{\text{MgCO}_3}}{P_{\text{CO}_2} \times P_{\text{MgO}}}

Step-by-Step Solution

For a heterogeneous equilibrium involving pure solids and gases, the concentration or partial pressure of pure solids is taken as constant (or unity) . The given reaction is: MgCO3(s)MgO(s)+CO2(g)\text{MgCO}_3(s) \rightleftharpoons \text{MgO}(s) + \text{CO}_2(g) Since MgCO3\text{MgCO}_3 and MgO\text{MgO} are pure solids, their partial pressures are not included in the equilibrium constant expression. Therefore, Kp=PCO2K_p = P_{\text{CO}_2} .

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