A mixture of 2.3 g formic acid and 4.5 g oxalic acid is treated with conc. H2SO4. The evolved gaseous mixture is passed through KOH pellets. Weight (in g) of the remaining product at STP will be:
A
1.4
B
3
C
2.8
D
4.4
Step-by-Step Solution
Formic acid (HCOOH) and oxalic acid (H2C2O4) undergo dehydration in the presence of concentrated H2SO4.
Dehydration of formic acid:
HCOOHconc. H2SO4H2O+CO
Molar mass of HCOOH=46 g mol−1.
Moles of HCOOH=46 g mol−12.3 g=0.05 mol.
Thus, 0.05 mol of CO is produced.
Dehydration of oxalic acid:
H2C2O4conc. H2SO4H2O+CO+CO2
Molar mass of H2C2O4=90 g mol−1 .
Moles of H2C2O4=90 g mol−14.5 g=0.05 mol.
Thus, 0.05 mol of CO and 0.05 mol of CO2 are produced.
Total moles of CO evolved =0.05+0.05=0.1 mol.
Total moles of CO2 evolved =0.05 mol.
When the gaseous mixture is passed through KOH pellets, CO2 is absorbed by KOH to form K2CO3.
The remaining gaseous product is only CO.
Weight of the remaining product (CO) =Moles×Molar mass
Weight of CO=0.1 mol×28 g mol−1=2.8 g.
Practice Mode Available
Master this Topic on Sushrut
Join thousands of students and practice with AI-generated mock tests.