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NEET CHEMISTRYMedium

A mixture of 2.3 g2.3 \text{ g} formic acid and 4.5 g4.5 \text{ g} oxalic acid is treated with conc. H2SO4\text{H}_2\text{SO}_4. The evolved gaseous mixture is passed through KOH\text{KOH} pellets. Weight (in g) of the remaining product at STP will be:

A

1.4

B

3

C

2.8

D

4.4

Step-by-Step Solution

Formic acid (HCOOH\text{HCOOH}) and oxalic acid (H2C2O4\text{H}_2\text{C}_2\text{O}_4) undergo dehydration in the presence of concentrated H2SO4\text{H}_2\text{SO}_4.

  1. Dehydration of formic acid: HCOOHconc. H2SO4H2O+CO\text{HCOOH} \xrightarrow{\text{conc. H}_2\text{SO}_4} \text{H}_2\text{O} + \text{CO} Molar mass of HCOOH=46 g mol1\text{HCOOH} = 46 \text{ g mol}^{-1}. Moles of HCOOH=2.3 g46 g mol1=0.05 mol\text{HCOOH} = \frac{2.3 \text{ g}}{46 \text{ g mol}^{-1}} = 0.05 \text{ mol}. Thus, 0.05 mol0.05 \text{ mol} of CO\text{CO} is produced.

  2. Dehydration of oxalic acid: H2C2O4conc. H2SO4H2O+CO+CO2\text{H}_2\text{C}_2\text{O}_4 \xrightarrow{\text{conc. H}_2\text{SO}_4} \text{H}_2\text{O} + \text{CO} + \text{CO}_2 Molar mass of H2C2O4=90 g mol1\text{H}_2\text{C}_2\text{O}_4 = 90 \text{ g mol}^{-1} . Moles of H2C2O4=4.5 g90 g mol1=0.05 mol\text{H}_2\text{C}_2\text{O}_4 = \frac{4.5 \text{ g}}{90 \text{ g mol}^{-1}} = 0.05 \text{ mol}. Thus, 0.05 mol0.05 \text{ mol} of CO\text{CO} and 0.05 mol0.05 \text{ mol} of CO2\text{CO}_2 are produced.

Total moles of CO\text{CO} evolved =0.05+0.05=0.1 mol= 0.05 + 0.05 = 0.1 \text{ mol}. Total moles of CO2\text{CO}_2 evolved =0.05 mol= 0.05 \text{ mol}.

When the gaseous mixture is passed through KOH\text{KOH} pellets, CO2\text{CO}_2 is absorbed by KOH\text{KOH} to form K2CO3\text{K}_2\text{CO}_3. The remaining gaseous product is only CO\text{CO}. Weight of the remaining product (CO\text{CO}) =Moles×Molar mass= \text{Moles} \times \text{Molar mass} Weight of CO=0.1 mol×28 g mol1=2.8 g\text{CO} = 0.1 \text{ mol} \times 28 \text{ g mol}^{-1} = 2.8 \text{ g}.

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