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NEET CHEMISTRYMedium

Given below are two statements: Statement I: Cr2+Cr^{2+} is oxidising agent and Mn3+Mn^{3+} is a reducing agent in nature. Statement II: Sc3+Sc^{3+} compounds are repelled by the applied magnetic field. In light of the above statements, choose the most appropriate answer from the options given below:

A

Both I and II are correct.

B

Both I and II are incorrect.

C

I is correct but II is incorrect.

D

I is incorrect but II is correct.

Step-by-Step Solution

Statement I is incorrect: Cr2+Cr^{2+} acts as a strong reducing agent because losing an electron oxidises it to Cr3+Cr^{3+}, which has a highly stable half-filled t2g3t_{2g}^3 configuration. On the other hand, Mn3+Mn^{3+} acts as a strong oxidising agent because accepting an electron reduces it to Mn2+Mn^{2+}, which has a highly stable half-filled d5d^5 configuration . Statement II is correct: Scandium in its +3 oxidation state (Sc3+Sc^{3+}) has a 3d03d^0 electronic configuration. Since it has zero unpaired electrons, it is diamagnetic. Diamagnetic substances are repelled by an applied magnetic field .

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