Back to Directory
NEET CHEMISTRYMedium

Consider the change in oxidation state of Bromine corresponding to different emf values as shown in the diagram below. Then the species undergoing disproportionation is:

A

BrO3\text{BrO}_3^-

B

BrO4\text{BrO}_4^-

C

Br2\text{Br}_2

D

HBrO\text{HBrO}

Step-by-Step Solution

For a species to undergo disproportionation, the standard reduction potential of the reaction to its right (reduction) must be greater than the standard reduction potential of the reaction to its left (from which it was formed by reduction). In other words, Eright>EleftE^\circ_{\text{right}} > E^\circ_{\text{left}}. Based on standard Latimer diagram values for bromine in acidic medium, the reduction potential of HBrO\text{HBrO} to Br2\text{Br}_2 is +1.59 V+1.59 \text{ V}, which is greater than the reduction potential of BrO3\text{BrO}_3^- to HBrO\text{HBrO} (+1.50 V+1.50 \text{ V}). Therefore, HBrO\text{HBrO} is thermodynamically unstable and spontaneously disproportionates into BrO3\text{BrO}_3^- and Br2\text{Br}_2.

Practice Mode Available

Master this Topic on Sushrut

Join thousands of students and practice with AI-generated mock tests.

Get Started
Solved: CHEMISTRY Question for NEET | Sushrut