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NEET CHEMISTRYMedium

Which mixture of the solutions will lead to the formation of negatively charged colloidal [AgI]I[AgI]I^- sol ?

A

50 mL of 1 M AgNO3AgNO_3 + 50 mL of 1.5 M KIKI

B

50 mL of 1 M AgNO3AgNO_3 + 50 mL of 2 M KIKI

C

50 mL of 2 M AgNO3AgNO_3 + 50 mL of 1.5 M KIKI

D

50 mL of 0.1 M AgNO3AgNO_3 + 50 mL of 0.1 M KIKI

Step-by-Step Solution

Generally charge present on the colloid is due to adsorption of common ion from dispersion medium. Millimole of KIKI is maximum in option (2) (50×2=10050 \times 2 = 100) so act as solvent and anion II^- is adsorbed by the colloid AgIAgI formed. AgNO3+KIAgI+KNO3AgNO_3 + KI \rightarrow AgI + KNO_3.

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