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NEET CHEMISTRYMedium

The correct electronic configuration of Gadolinium (Atomic number = 64) is:

A

[Xe]4f86d2[\text{Xe}]4f^8 6d^2

B

[Xe]4f95s1[\text{Xe}]4f^9 5s^1

C

[Xe]4f75d16s2[\text{Xe}]4f^7 5d^1 6s^2

D

[Xe]4f65d26s2[\text{Xe}]4f^6 5d^2 6s^2

Step-by-Step Solution

Gadolinium (Gd, Z = 64) belongs to the lanthanoid series. Its nearest noble gas is Xenon (Xe, Z = 54). Out of the remaining 10 electrons, two fill the 6s6s orbital (6s26s^2). The expected distribution for the rest of the electrons would be 4f84f^8. However, an exactly half-filled ff-subshell (f7f^7) confers extra stability to the atom. Therefore, one electron shifts to the 5d5d orbital, giving the actual ground state electronic configuration as [Xe]4f75d16s2[\text{Xe}]4f^7 5d^1 6s^2.

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