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NEET CHEMISTRYMedium

Identify the correct statements from the following: (a) CO2(g)CO_2(g) is used as a refrigerant for ice cream and frozen food. (b) The structure of C60C_{60} contains twelve six-carbon rings and twenty-five five-carbon rings. (c) ZSM-5, a type of zeolite, is used to convert alcohols into gasoline. (d) CO is a colorless and odorless gas.

A

(a) and (c) only

B

(b) and (c) only

C

(c) and (d) only

D

(a), (c) and (d) only

Step-by-Step Solution

  1. Statement (a) is Incorrect: Solid CO2CO_2 (known as Dry Ice), not gaseous CO2CO_2, is used as a refrigerant for ice cream and frozen food because it sublimes directly to gas at –78°C, providing cooling without leaving liquid residue [Source 105 mentions sublimation of dry ice].
  2. Statement (b) is Incorrect: Buckminsterfullerene (C60C_{60}) has a shape like a soccer ball. It contains 20 six-membered rings (hexagons) and 12 five-membered rings (pentagons), not the numbers stated in the option.
  3. Statement (c) is Correct: ZSM-5 is a shape-selective zeolite catalyst with a pore structure that allows it to convert alcohols (like methanol) directly into gasoline (a mixture of hydrocarbons) by dehydration.
  4. Statement (d) is Correct: Carbon monoxide (CO) is a colorless, odorless, and almost water-insoluble gas. Its odorless nature makes it particularly dangerous as a pollutant [Source 123 discusses CO toxicity].
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