The standard enthalpy of neutralisation for the reaction between a strong acid and a strong base in dilute aqueous solution is approximately –57.33 kJ mol⁻¹, representing the formation of one mole of water from H+(aq) and OH−(aq) ions [Source knowledge]. However, for the reaction involving a solid basic oxide like MgO, we apply Hess's Law using the standard enthalpies of formation (ΔfH∘) found in the sources:
-
Identify Enthalpy Values (at 298 K):
ΔfH∘[Mg2+(aq)]=−466.85 kJ mol−1 ΔfH∘[H2O(l)]=−285.83 kJ mol−1
ΔfH∘[MgO(s)]=−601.70 kJ mol−1 ΔfH∘[H+(aq)]=0 kJ mol−1 (by convention)
-
Calculate Reaction Enthalpy (ΔrH∘):
The net ionic equation is MgO(s)+2H+(aq)→Mg2+(aq)+H2O(l).
ΔrH∘=[ΔfH∘(Mg2+,aq)+ΔfH∘(H2O,l)]−[ΔfH∘(MgO,s)+2×ΔfH∘(H+,aq)]
ΔrH∘=[(−466.85)+(−285.83)]−[(−601.70)+0]
ΔrH∘=−752.68−(−601.70)=−150.98 kJ mol−1.
Since –150.98 kJ mol⁻¹ is numerically less than –57.33 kJ mol⁻¹ (more exothermic), the correct option is A.