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NEET CHEMISTRYHard

The absolute enthalpy of neutralisation of the reaction MgO(s)+2HCl(aq)ightarrowMgCl2(aq)+H2O(l)MgO(s) + 2HCl(aq) ightarrow MgCl_{2}(aq) + H_{2}O(l) will be [CBSE PMT 2005]:

A

Less than –57.33 kJ mol⁻¹

B

–57.33 kJ mol⁻¹

C

Greater than –57.33 kJ mol⁻¹

D

57.33 kJ mol⁻¹

Step-by-Step Solution

The standard enthalpy of neutralisation for the reaction between a strong acid and a strong base in dilute aqueous solution is approximately –57.33 kJ mol⁻¹, representing the formation of one mole of water from H+(aq)H^{+}(aq) and OH(aq)OH^{-}(aq) ions [Source knowledge]. However, for the reaction involving a solid basic oxide like MgO, we apply Hess's Law using the standard enthalpies of formation (ΔfH\Delta_{f}H^{\circ}) found in the sources:

  1. Identify Enthalpy Values (at 298 K): ΔfH[Mg2+(aq)]=466.85 kJ mol1\Delta_{f}H^{\circ} [Mg^{2+}(aq)] = -466.85 \text{ kJ mol}^{-1} ΔfH[H2O(l)]=285.83 kJ mol1\Delta_{f}H^{\circ} [H_{2}O(l)] = -285.83 \text{ kJ mol}^{-1} ΔfH[MgO(s)]=601.70 kJ mol1\Delta_{f}H^{\circ} [MgO(s)] = -601.70 \text{ kJ mol}^{-1} ΔfH[H+(aq)]=0 kJ mol1\Delta_{f}H^{\circ} [H^{+}(aq)] = 0 \text{ kJ mol}^{-1} (by convention)

  2. Calculate Reaction Enthalpy (ΔrH\Delta_{r}H^{\circ}): The net ionic equation is MgO(s)+2H+(aq)Mg2+(aq)+H2O(l)MgO(s) + 2H^{+}(aq) \rightarrow Mg^{2+}(aq) + H_{2}O(l). ΔrH=[ΔfH(Mg2+,aq)+ΔfH(H2O,l)][ΔfH(MgO,s)+2×ΔfH(H+,aq)]\Delta_{r}H^{\circ} = [\Delta_{f}H^{\circ}(Mg^{2+}, aq) + \Delta_{f}H^{\circ}(H_{2}O, l)] - [\Delta_{f}H^{\circ}(MgO, s) + 2 \times \Delta_{f}H^{\circ}(H^{+}, aq)] ΔrH=[(466.85)+(285.83)][(601.70)+0]\Delta_{r}H^{\circ} = [(-466.85) + (-285.83)] - [(-601.70) + 0] ΔrH=752.68(601.70)=150.98 kJ mol1\Delta_{r}H^{\circ} = -752.68 - (-601.70) = -150.98 \text{ kJ mol}^{-1}.

Since –150.98 kJ mol⁻¹ is numerically less than –57.33 kJ mol⁻¹ (more exothermic), the correct option is A.

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