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NEET CHEMISTRYEasy

Camphor is often used in molecular mass determination because:

A

It has a very high cryoscopic constant

B

It is volatile

C

It is a solvent for organic substances

D

It is readily available

Step-by-Step Solution

The depression in freezing point (ΔTf\Delta T_f) is directly proportional to the molality (mm) of the solute and the cryoscopic constant (KfK_f) of the solvent, given by the equation ΔTf=Kfm\Delta T_f = K_f \cdot m . In molecular mass determination (specifically Rast's method), camphor is preferred as a solvent because it possesses a very high cryoscopic constant (Kf39.7 K kg mol1K_f \approx 39.7 \text{ K kg mol}^{-1}). A high KfK_f value ensures that even a small amount of solute produces a large, easily measurable depression in the freezing point, increasing the accuracy of the molar mass calculation.

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