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NEET CHEMISTRYMedium

For the reaction, 2AB2A \rightarrow B, rate=k[A]2\text{rate} = k[A]^2. If the concentration of reactant is doubled, then the: (a) rate of reaction will be doubled. (b) rate constant will remain unchanged, however rate of reaction is directly proportional to the rate constant. (c) rate constant will change since the rate of reaction and rate constant are directly proportional to each other. (d) rate of reaction will increase by four times. Identify the set of correct statements and choose the correct answer from the options given below:

A

(a) and (c) only

B

(a) and (b) only

C

(b) and (d) only

D

(c) and (d) only

Step-by-Step Solution

For the reaction 2AB2A \rightarrow B, the rate law is given as Rate=k[A]2\text{Rate} = k[A]^2. If the concentration of A is doubled, the new rate will be Rate=k(2[A])2=4k[A]2=4×Rate\text{Rate}' = k(2[A])^2 = 4k[A]^2 = 4 \times \text{Rate}. Thus, the rate of reaction will increase by four times, making statement (d) correct. The rate constant (kk) is a proportionality constant that depends on temperature and the presence of a catalyst, but it is independent of the initial concentrations of the reactants. Therefore, the rate constant will remain unchanged. Also, from the rate equation, the rate of reaction is directly proportional to the rate constant. This makes statement (b) correct. Therefore, the correct statements are (b) and (d).

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