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NEET CHEMISTRYMedium

The incorrect statement among the following is:

A

Lanthanoids are good conductors of heat and electricity.

B

Actinoids are highly reactive metals, especially when finely divided.

C

Actinoid contraction is greater for element to element than Lanthanoid contraction.

D

Most of the trivalent Lanthanoid ions are colourless in the solid-state.

Step-by-Step Solution

Let us evaluate all the given statements:

  1. Statement 1 is correct: Lanthanoids are silvery-white soft metals. They possess typical metallic structures and are good conductors of heat and electricity .
  2. Statement 2 is correct: Actinoids are highly reactive metals, particularly when they are in a finely divided state .
  3. Statement 3 is correct: The actinoid contraction is greater from element to element than the lanthanoid contraction. This occurs because the 5f5f electrons provide poorer shielding from the increasing nuclear charge compared to the 4f4f electrons .
  4. Statement 4 is incorrect: Many trivalent lanthanoid ions are actually coloured, both in the solid state and in aqueous solutions. This colour is primarily attributed to the presence of ff electrons, which allow for ff-ff electronic transitions .
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