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NEET CHEMISTRYMedium

0.50.5 molal aqueous solution of a weak acid (HX\text{HX}) is 20%20\% ionised. If KfK_f for water is 1.86 K kg mol11.86 \text{ K kg mol}^{-1}, the lowering in freezing point of the solution is:

A

1.12 K-1.12 \text{ K}

B

0.56 K0.56 \text{ K}

C

1.12 K1.12 \text{ K}

D

0.56 K-0.56 \text{ K}

Step-by-Step Solution

For the weak acid HX\text{HX}, the ionization reaction is: HXH++X\text{HX} \rightleftharpoons \text{H}^+ + \text{X}^- The number of ions produced per molecule upon dissociation, n=2n = 2. Given, the degree of ionization α=20%=0.2\alpha = 20\% = 0.2.

The van't Hoff factor (ii) is calculated as: i=1+α(n1)=1+0.2(21)=1.2i = 1 + \alpha(n - 1) = 1 + 0.2(2 - 1) = 1.2

The depression (lowering) in freezing point is given by the formula: ΔTf=i×Kf×m\Delta T_f = i \times K_f \times m

Given values: Molality, m=0.5 mol kg1m = 0.5 \text{ mol kg}^{-1} Molal depression constant, Kf=1.86 K kg mol1K_f = 1.86 \text{ K kg mol}^{-1}

Substituting the values: ΔTf=1.2×1.86×0.5=1.116 K1.12 K\Delta T_f = 1.2 \times 1.86 \times 0.5 = 1.116 \text{ K} \approx 1.12 \text{ K}.

Therefore, the lowering in freezing point of the solution is 1.12 K1.12 \text{ K}.

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