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NEET CHEMISTRYMedium

Which of the two species, NO3NO_{3}^{-} or H3O+H_{3}O^{+}, has the correctly described properties listed below?

A

Isostructural with the same hybridization for the central atom.

B

Isostructural with different hybridization for the central atom.

C

Similar in hybridization for the central atom with different structures.

D

Dissimilar in hybridization for the central atom with different structures.

Step-by-Step Solution

According to the principles of chemical bonding and molecular geometry found in the sources, the properties of the two species are determined as follows:

  1. NO3NO_{3}^{-} (Nitrate ion): The central nitrogen atom has five valence electrons, and the ion carries a negative charge. It is isoelectronic with the carbonate ion (CO32CO_{3}^{2-}) . The nitrogen atom undergoes sp2sp^{2} hybridisation and adopts a trigonal planar structure to accommodate three bonding domains with no lone pairs on the central atom .
  2. H3O+H_{3}O^{+} (Hydronium ion): The central oxygen atom has six valence electrons, one of which is lost to form the cation. It forms three bonds with hydrogen atoms and retains one lone pair. As stated in the sources, this results in sp3sp^{3} hybridisation and a trigonal pyramidal geometry .

Because NO3NO_{3}^{-} is sp2sp^{2} (planar) and H3O+H_{3}O^{+} is sp3sp^{3} (pyramidal), the two species have dissimilar hybridisation for the central atom and different structures.

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