Back to Directory
NEET CHEMISTRYMedium

The total number of possible isomers for the complex [Co(en)2Cl2]Cl[Co(en)_2Cl_2]Cl are: [enen - ethylenediamine]

A

2

B

1

C

3

D

4

Step-by-Step Solution

The complex [Co(en)2Cl2]Cl[Co(en)_2Cl_2]Cl contains the complex cation [Co(en)2Cl2]+[Co(en)_2Cl_2]^+. This complex ion exhibits both geometrical and optical isomerism.

  1. Geometrical Isomerism: It can exist in cis and trans spatial arrangements.
  2. Optical Isomerism: The trans-isomer possesses a plane of symmetry and is thus optically inactive (achiral). However, the cis-isomer lacks a plane of symmetry and is optically active, existing as a pair of non-superimposable mirror images (dextro and laevo enantiomers). Therefore, the total number of possible stereoisomers is 3 (one trans isomer and two enantiomeric cis isomers).
Practice Mode Available

Master this Topic on Sushrut

Join thousands of students and practice with AI-generated mock tests.

Get Started