An acid that forms an anhydride (X) on heating and an acid imide (Y) on strong heating with ammonia is:
A
Option 1
B
Option 2
C
Option 3
D
Option 4
Step-by-Step Solution
The reactions described correspond to the chemical behavior of Phthalic acid (benzene-1,2-dicarboxylic acid).
Formation of Anhydride: Dicarboxylic acids with carboxyl groups in proper positions (like 1,2-positions) undergo dehydration on heating to form stable cyclic anhydrides. Phthalic acid loses a molecule of water to form Phthalic anhydride (X).
C6H4(COOH)2ΔPhthalic anhydride+H2O
Formation of Imide: When treated with ammonia, carboxylic acids form ammonium salts. On strong heating, ammonium phthalate loses water to form Phthalimide (Y).
C6H4(COOH)2+NH3⇌Ammonium phthalateΔPhthalimide+2H2O
(Note: Succinic acid also shows similar behavior, forming succinic anhydride and succinimide, but Phthalic acid is the specific aromatic example often cited in this context in NEET/NCERT exams).
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