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NEET CHEMISTRYMedium

Which of the following is the most basic oxide?

A

Al₂O₃

B

Sb₂O₃

C

Bi₂O₃

D

SeO₂

Step-by-Step Solution

  1. Analyze Periodic Trends: Metallic oxides are generally basic, while non-metallic oxides are acidic. Within a group, basic character increases down the group as metallic character increases. Across a period, acidic character increases.
  2. Analyze Al2O3Al_2O_3 (Aluminium Oxide): Aluminium is amphoteric. Al2O3Al_2O_3 reacts with both acids and bases [Class 12 Chemistry, Unit 4, Sec 4.4]. It is amphoteric.
  3. Analyze Sb2O3Sb_2O_3 (Antimony(III) Oxide): Antimony is a metalloid (Group 15). Its oxide is amphoteric.
  4. Analyze SeO2SeO_2 (Selenium Dioxide): Selenium is a non-metal (Group 16). Non-metallic oxides are acidic. SeO2SeO_2 is acidic.
  5. Analyze Bi2O3Bi_2O_3 (Bismuth(III) Oxide): Bismuth is a metal (Group 15, below Antimony). As we move down Group 15, the metallic character increases (N<P<As<Sb<BiN < P < As < Sb < Bi). Consequently, the basic nature of their oxides increases. Bi2O3Bi_2O_3 is purely basic.
  6. Conclusion: Among the given options, Bi2O3Bi_2O_3 is the only purely basic oxide.
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