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NEET CHEMISTRYMedium

Identify the incorrect statement from the following:

A

The shapes of dxy,dyzd_{xy}, d_{yz}, and dzxd_{zx} orbitals are similar to each other; and dx2y2d_{x^2-y^2} and dz2d_{z^2} are similar to each other.

B

All the five 5d5d orbitals are different in size when compared to the respective 4d4d orbitals.

C

All the five 4d4d orbitals have shapes similar to the respective 3d3d orbitals.

D

In an atom, all the five 3d3d orbitals are equal in energy in free state.

Step-by-Step Solution

According to NCERT, the five dd-orbitals are designated as dxy,dyz,dxz,dx2y2d_{xy}, d_{yz}, d_{xz}, d_{x^2-y^2}, and dz2d_{z^2}. The shapes of the first four (dxy,dyz,dxz,dx2y2d_{xy}, d_{yz}, d_{xz}, d_{x^2-y^2}) are similar to each other (double dumbbell or cloverleaf shape), whereas the shape of the fifth one, dz2d_{z^2}, is different (doughnut shape/dumbbell with a ring). Therefore, the statement claiming dx2y2d_{x^2-y^2} and dz2d_{z^2} are similar is incorrect.

Other statements are correct:

  • Size increases with principal quantum number (nn), so 5d5d orbitals are larger than 4d4d orbitals.
  • Shapes of orbitals depend on the azimuthal quantum number (ll), not nn, so 4d4d and 3d3d have similar shapes.
  • In a free isolated atom, all five dd-orbitals of a specific shell are degenerate (equal in energy) .
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