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NEET CHEMISTRYMedium

Equal volumes of three acid solutions of pH 3, 4 and 5 are mixed in a vessel. What will be the H+H^+ ion concentration in the mixture?

A

1.11×104 M1.11 \times 10^{-4} \text{ M}

B

3.7×104 M3.7 \times 10^{-4} \text{ M}

C

3.7×103 M3.7 \times 10^{-3} \text{ M}

D

1.11×103 M1.11 \times 10^{-3} \text{ M}

Step-by-Step Solution

The concentration of H+H^+ ions can be calculated from the pH values: [H+]=10pH[H^+] = 10^{-pH} For the first solution (pH = 3): [H+]1=103 M[H^+]_1 = 10^{-3}\text{ M} For the second solution (pH = 4): [H+]2=104 M[H^+]_2 = 10^{-4}\text{ M} For the third solution (pH = 5): [H+]3=105 M[H^+]_3 = 10^{-5}\text{ M} Let the volume of each solution be VV. Total moles of H+H^+ in the mixture = (103+104+105)×V=(100×105+10×105+1×105)×V=111×105×V=1.11×103×V(10^{-3} + 10^{-4} + 10^{-5}) \times V = (100 \times 10^{-5} + 10 \times 10^{-5} + 1 \times 10^{-5}) \times V = 111 \times 10^{-5} \times V = 1.11 \times 10^{-3} \times V. Total volume of the mixture = V+V+V=3VV + V + V = 3V. The final H+H^+ ion concentration = Total moles of H+Total volume=1.11×103×V3V=0.37×103 M=3.7×104 M\frac{\text{Total moles of } H^+}{\text{Total volume}} = \frac{1.11 \times 10^{-3} \times V}{3V} = 0.37 \times 10^{-3}\text{ M} = 3.7 \times 10^{-4}\text{ M}.

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