According to the Arrhenius equation,
k=Ae−Ea/RT
Taking the natural logarithm on both sides yields:
lnk=−REa(T1)+lnA
Comparing this with the equation of a straight line, y=mx+c, the plot of lnk versus 1/T gives a straight line with slope m=−REa.
Given slope =−5×103 K
−REa=−5×103 K
Ea=5×103×R
Ea=5×103 K×8.314 J K−1 mol−1=41570 J mol−1=41.57 kJ mol−1≈41.5 kJ mol−1.