Which of the following compounds has a higher hydration energy than the lattice energy?
For an ionic compound to dissolve in water, its hydration energy must exceed its lattice energy. Among the alkaline earth metal sulphates, the solubility in water decreases down the group from to . Both and are readily soluble in water because their hydration energies are higher than their lattice energies due to the smaller size of and ions. Conversely, as we move down the group, the hydration energy decreases more rapidly than the lattice energy. Hence, the lattice energies of , , and are higher than their hydration energies, making them sparingly soluble or insoluble.
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