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NEET CHEMISTRYMedium

The ionisation constant of ammonium hydroxide is 1.77×1051.77 \times 10^{-5} at 298 K. Hydrolysis constant of ammonium chloride is:

A

5.65×10105.65 \times 10^{-10}

B

6.50×10126.50 \times 10^{-12}

C

5.65×10135.65 \times 10^{-13}

D

5.65×10125.65 \times 10^{-12}

Step-by-Step Solution

Ammonium chloride (NH4ClNH_4Cl) is a salt formed by a strong acid (HClHCl) and a weak base (NH4OHNH_4OH). In an aqueous solution, the ammonium ion (NH4+NH_4^+) undergoes hydrolysis to form NH4OHNH_4OH and H+H^+. The hydrolysis constant (KhK_h) for a salt of a weak base and strong acid is given by the expression: Kh=KwKbK_h = \frac{K_w}{K_b} where KwK_w is the ionic product of water (1.0×10141.0 \times 10^{-14} at 298 K) and KbK_b is the ionization constant of the weak base. Given Kb=1.77×105K_b = 1.77 \times 10^{-5}. Substituting the values: Kh=1.0×10141.77×1050.5649×109=5.65×1010K_h = \frac{1.0 \times 10^{-14}}{1.77 \times 10^{-5}} \approx 0.5649 \times 10^{-9} = 5.65 \times 10^{-10}.

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