According to the principles of chemical bonding and molecular structure:
- Electronic Configuration: Boron (B, atomic number 5) has the electronic configuration 1s22s22p1 . In its excited state, one electron from the 2s orbital is promoted to a 2p orbital, providing three unpaired electrons .
- Hybridisation: These three orbitals (one s and two p) intermix to form three equivalent sp2 hybrid orbitals .
- Geometry: These sp2 hybrid orbitals are oriented in a trigonal planar arrangement with bond angles of 120∘ .
- Electron Count: Boron forms three sigma bonds with three fluorine atoms. Each bond consists of a shared pair of electrons, resulting in a total of 6 valence electrons around the central boron atom .
- Electron Deficiency: Since the boron atom has only 6 electrons in its valence shell, it does not complete its octet, which explains why BF3 is an electron-deficient compound and acts as a Lewis acid .
Therefore, the hybridisation is sp2 and the number of electrons around the central atom is 6.