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NEET CHEMISTRYMedium

It is because of the inability of ns2ns^2 electrons of the valence shell to participate in bonding that:

A

Sn2+\text{Sn}^{2+} is reducing while Pb4+\text{Pb}^{4+} is oxidising agent

B

Sn2+\text{Sn}^{2+} is oxidising while Pb4+\text{Pb}^{4+} is reducing agent

C

Sn2+\text{Sn}^{2+} and Pb2+\text{Pb}^{2+} are both oxidising and reducing agent

D

Sn4+\text{Sn}^{4+} is reducing while Pb4+\text{Pb}^{4+} is oxidising agent

Step-by-Step Solution

Due to the inert pair effect, the reluctance of valence ns2ns^2 electrons to participate in bonding increases down the group. Therefore, in the carbon family (Group 14), the stability of the +4+4 oxidation state decreases and that of the +2+2 oxidation state increases as we move from Ge\text{Ge} to Pb\text{Pb}. Consequently, for Tin (Sn\text{Sn}), the +4+4 state is more stable than the +2+2 state, making Sn2+\text{Sn}^{2+} a reducing agent as it readily oxidises to Sn4+\text{Sn}^{4+}. Conversely, for Lead (Pb\text{Pb}), the +2+2 state is more stable than the +4+4 state. Thus, Pb4+\text{Pb}^{4+} acts as a strong oxidising agent because it readily gets reduced to Pb2+\text{Pb}^{2+}.

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