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NEET CHEMISTRYMedium

A pair among the following have nearly the same atomic radii: (Numbers in the parenthesis are atomic numbers).

A

Ti (22)\text{Ti (22)} and Zr (40)\text{Zr (40)}

B

Zr (40)\text{Zr (40)} and Nb (41)\text{Nb (41)}

C

Zr (40)\text{Zr (40)} and Hf (72)\text{Hf (72)}

D

Zr (40)\text{Zr (40)} and Ta (73)\text{Ta (73)}

Step-by-Step Solution

The atomic radii of the elements of the second and third transition series are almost similar. This is due to lanthanoid contraction. The filling of 4f4f orbitals before the 5d5d orbitals results in a regular decrease in atomic radii, which compensates for the expected increase in atomic size with increasing atomic number. For example, Zirconium (Zr, atomic number 40) has an atomic radius of 160 pm, and Hafnium (Hf, atomic number 72) has an atomic radius of 159 pm.

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