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Identify the correct statement for the change of Gibbs energy for a system (ΔGsystem\Delta G_{\text{system}}) at constant temperature and pressure:

A

If ΔGsystem>0\Delta G_{\text{system}} > 0, the process is spontaneous

B

If ΔGsystem=0\Delta G_{\text{system}} = 0, the system has attained equilibrium

C

If ΔGsystem=0\Delta G_{\text{system}} = 0, the system is still moving in a particular direction

D

If ΔGsystem<0\Delta G_{\text{system}} < 0, the process is not spontaneous

Step-by-Step Solution

The change in Gibbs free energy (ΔG\Delta G) provides a criterion for the spontaneity of a process at constant temperature and pressure. If ΔGsystem<0\Delta G_{\text{system}} < 0, the process is spontaneous. If ΔGsystem>0\Delta G_{\text{system}} > 0, the process is non-spontaneous. If ΔGsystem=0\Delta G_{\text{system}} = 0, the system has attained a state of equilibrium, meaning the rate of the forward process equals the rate of the backward process, and there is no net movement in any particular direction .

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