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NEET CHEMISTRYMedium

Which of the following methods is incorrect for the synthesis of alkenes?

A

Treatment of alkynes with Na in liquid NH3\text{NH}_3

B

Heating alkyl halides with alcoholic KOH\text{KOH}

C

Treating alkyl halides in aqueous KOH\text{KOH} solution

D

Treating vicinal dihalides with Zn metal

Step-by-Step Solution

Treating alkyl halides with aqueous KOH\text{KOH} leads to a nucleophilic substitution reaction, forming alcohols as the major product rather than alkenes . In contrast, heating alkyl halides with alcoholic KOH\text{KOH} causes a β\beta-elimination (dehydrohalogenation) reaction, which successfully forms alkenes . Additionally, the reduction of alkynes with sodium in liquid NH3\text{NH}_3 produces trans-alkenes , and the treatment of vicinal dihalides with zinc metal undergoes dehalogenation to form alkenes . Therefore, the use of aqueous KOH\text{KOH} is the incorrect method for alkene synthesis.

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