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NEET CHEMISTRYMedium

RMgX+CO2dry etherYH3O+RCOOHRMgX + CO_2 \xrightarrow{\text{dry ether}} Y \xrightarrow{H_3O^+} RCOOH What is Y in the above reaction?

A

(RCOO)2Mg(RCOO)_2Mg

B

RCOOMg+XRCOO^-Mg^+X

C

R3COMg+XR_3CO^-Mg^+X

D

RCOOX+RCOO^-X^+

Step-by-Step Solution

Grignard reagents (RMgXRMgX) react with solid carbon dioxide (dry ice) in the presence of dry ether to undergo nucleophilic addition. The nucleophilic alkyl or aryl group (RR^-) from the Grignard reagent attacks the electrophilic carbon atom of CO2CO_2. This results in the formation of an intermediate adduct, which is a magnesium salt of a carboxylic acid represented as RCOOMg+XRCOO^-Mg^+X. Subsequent hydrolysis of this intermediate salt with a dilute acid (H3O+H_3O^+) yields the corresponding carboxylic acid (RCOOHRCOOH).

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