The strong field nature of as a ligand can be attributed to:
It is a pseudohalide.
It can accept electrons from metal species.
It forms high-spin complexes with metal species.
It possesses a negative charge.
The strong field nature of the ligand is due to its -acceptor behavior. In addition to donating a lone pair of electrons to form a -bond with the central metal atom/ion, it can also accept electron density from the filled -orbitals of the metal ion into its vacant antibonding orbitals through back-bonding. This synergic interaction increases the crystal field splitting energy (), making a strong field ligand.
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