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NEET CHEMISTRYMedium

The strong field nature of CNCN^- as a ligand can be attributed to:

A

It is a pseudohalide.

B

It can accept electrons from metal species.

C

It forms high-spin complexes with metal species.

D

It possesses a negative charge.

Step-by-Step Solution

The strong field nature of the CNCN^- ligand is due to its π\pi-acceptor behavior. In addition to donating a lone pair of electrons to form a σ\sigma-bond with the central metal atom/ion, it can also accept electron density from the filled dd-orbitals of the metal ion into its vacant antibonding π\pi^* orbitals through back-bonding. This synergic interaction increases the crystal field splitting energy (Δ0\Delta_0), making CNCN^- a strong field ligand.

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