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NEET CHEMISTRYMedium

Zn gives H₂ gas with H₂SO₄ and HCl but not with HNO₃ because:

A

Zn acts as an oxidizing agent when it reacts with HNO₃

B

HNO₃ is weaker acid than H₂SO₄ and HCl

C

In the electrochemical series, Zn is above hydrogen

D

NO₃⁻ is reduced in preference to hydronium ion

Step-by-Step Solution

Zinc reacts with non-oxidizing acids like HCl and H₂SO₄ to evolve dihydrogen gas because Zinc has a lower standard reduction potential (E0=0.76VE^0 = -0.76 V) than hydrogen (E0=0.00VE^0 = 0.00 V), allowing it to reduce H+H^+ ions . However, HNO3HNO_3 is a strong oxidizing agent. When metals (with exceptions like Mg and Mn with very dilute acid) react with HNO3HNO_3, the hydrogen initially produced is oxidized to water, while the nitrate ion (NO3NO_3^-) is reduced to various nitrogen oxides (NO,NO2NO, NO_2, etc.) . Thermodynamically, the reduction of the nitrate ion occurs in preference to the reduction of the hydronium ion (H+H^+) to H2H_2 gas.

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