Zn gives H₂ gas with H₂SO₄ and HCl but not with HNO₃ because:
Zn acts as an oxidizing agent when it reacts with HNO₃
HNO₃ is weaker acid than H₂SO₄ and HCl
In the electrochemical series, Zn is above hydrogen
NO₃⁻ is reduced in preference to hydronium ion
Zinc reacts with non-oxidizing acids like HCl and H₂SO₄ to evolve dihydrogen gas because Zinc has a lower standard reduction potential () than hydrogen (), allowing it to reduce ions . However, is a strong oxidizing agent. When metals (with exceptions like Mg and Mn with very dilute acid) react with , the hydrogen initially produced is oxidized to water, while the nitrate ion () is reduced to various nitrogen oxides (, etc.) . Thermodynamically, the reduction of the nitrate ion occurs in preference to the reduction of the hydronium ion () to gas.
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