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NEET CHEMISTRYEasy

Percentage of C, H & N in a compound is given as follows: C=40%; H=13.33%; N=46.67% The empirical formula of the compound will be:

A

CH₂N

B

C₂H₄N

C

CH₄N

D

CH₃N

Step-by-Step Solution

  1. Determine the number of moles of each element: Assume a 100 g100\text{ g} sample of the compound.
  • Moles of Carbon (C): 40 g12 g/mol=3.33 mol\frac{40\text{ g}}{12\text{ g/mol}} = 3.33\text{ mol}
  • Moles of Hydrogen (H): 13.33 g1 g/mol=13.33 mol\frac{13.33\text{ g}}{1\text{ g/mol}} = 13.33\text{ mol}
  • Moles of Nitrogen (N): 46.67 g14 g/mol=3.33 mol\frac{46.67\text{ g}}{14\text{ g/mol}} = 3.33\text{ mol}
  1. Determine the simplest molar ratio: Divide the moles of each element by the smallest molar value (3.33 mol3.33\text{ mol}).
  • C: 3.333.33=1\frac{3.33}{3.33} = 1
  • H: 13.333.334\frac{13.33}{3.33} \approx 4
  • N: 3.333.33=1\frac{3.33}{3.33} = 1
  1. Conclusion: The simplest whole number ratio of C:H:N is 1:4:11:4:1. Therefore, the empirical formula is CH4N\text{CH}_4\text{N}.
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