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NEET CHEMISTRYMedium

Arrange the elements Li, Be, B, C, and N in increasing order of their first ionization enthalpies:

A

Li < B < Be < C < N

B

Li < Be < C < B < N

C

Li < Be < N < B < C

D

Li < Be < B < C < N

Step-by-Step Solution

Generally, ionization enthalpy increases across a period from left to right due to increasing effective nuclear charge. However, there is an anomaly between Group 2 (Be) and Group 13 (B). Beryllium has a stable, completely filled valence shell configuration (1s22s21s^2 2s^2), and the 2s electrons are more penetrating towards the nucleus. Boron (1s22s22p11s^2 2s^2 2p^1) has a single 2p electron which is shielded by the inner 2s electrons, making it easier to remove. Therefore, the ionization enthalpy of Boron is lower than that of Beryllium (B<BeB < Be). The general trend holds for the rest, placing Lithium first (alkali metal) and Carbon and Nitrogen following the increase in nuclear charge. Nitrogen has higher stability due to a half-filled p-subshell, further increasing its value. The correct order is Li<B<Be<C<NLi < B < Be < C < N.

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