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NEET CHEMISTRYMedium

If the EcellE^\circ_{\text{cell}} for a given reaction has a negative value, which of the following gives correct relationships for the values of ΔG\Delta G^\circ and KeqK_{\text{eq}}?

A

ΔG>0;Keq<1\Delta G^\circ > 0; K_{\text{eq}} < 1

B

ΔG>0;Keq>1\Delta G^\circ > 0; K_{\text{eq}} > 1

C

ΔG<0;Keq>1\Delta G^\circ < 0; K_{\text{eq}} > 1

D

ΔG<0;Keq<1\Delta G^\circ < 0; K_{\text{eq}} < 1

Step-by-Step Solution

The standard Gibbs free energy change ΔG\Delta G^\circ is related to the standard cell potential EcellE^\circ_{\text{cell}} by the equation: ΔG=nFEcell\Delta G^\circ = -nFE^\circ_{\text{cell}} If EcellE^\circ_{\text{cell}} is negative, then ΔG\Delta G^\circ must be positive (ΔG>0\Delta G^\circ > 0). Furthermore, ΔG\Delta G^\circ is related to the equilibrium constant KeqK_{\text{eq}} by the equation: ΔG=2.303RTlogKeq\Delta G^\circ = -2.303 RT \log K_{\text{eq}} Since ΔG\Delta G^\circ is positive, logKeq\log K_{\text{eq}} must be negative. This means Keq<1K_{\text{eq}} < 1. Therefore, the correct relationship is ΔG>0\Delta G^\circ > 0 and Keq<1K_{\text{eq}} < 1.

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