Let the bond dissociation energies of X2, Y2, and XY be x, 0.5x, and x respectively.
The reaction for the formation of XY is:
21X2+21Y2→XY
The enthalpy of formation (ΔfH) is given by:
ΔfH=∑B.E. (reactants)−∑B.E. (products)
ΔfH=21B.E.(X2)+21B.E.(Y2)−B.E.(XY)
Given that ΔfH=−200 kJ mol−1:
−200=21(x)+21(0.5x)−x
−200=0.5x+0.25x−x
−200=−0.25x
x=0.25200=800 kJ mol−1
Therefore, the bond dissociation energy of X2 is 800 kJ mol−1.