Back to Directory
NEET CHEMISTRYMedium

The bond dissociation energies of X2X_2, Y2Y_2 and XYXY are in the ratio of 1:0.5:11 : 0.5 : 1. ΔH\Delta H for the formation of XYXY is 200 kJ mol1-200 \text{ kJ mol}^{-1}. The bond dissociation energy of X2X_2 will be:

A

200 kJ mol1200 \text{ kJ mol}^{-1}

B

100 kJ mol1100 \text{ kJ mol}^{-1}

C

800 kJ mol1800 \text{ kJ mol}^{-1}

D

400 kJ mol1400 \text{ kJ mol}^{-1}

Step-by-Step Solution

Let the bond dissociation energies of X2X_2, Y2Y_2, and XYXY be xx, 0.5x0.5x, and xx respectively. The reaction for the formation of XYXY is: 12X2+12Y2XY\frac{1}{2}X_2 + \frac{1}{2}Y_2 \rightarrow XY The enthalpy of formation (ΔfH\Delta_f H) is given by: ΔfH=B.E. (reactants)B.E. (products)\Delta_f H = \sum \text{B.E. (reactants)} - \sum \text{B.E. (products)} ΔfH=12B.E.(X2)+12B.E.(Y2)B.E.(XY)\Delta_f H = \frac{1}{2}\text{B.E.}(X_2) + \frac{1}{2}\text{B.E.}(Y_2) - \text{B.E.}(XY) Given that ΔfH=200 kJ mol1\Delta_f H = -200 \text{ kJ mol}^{-1}: 200=12(x)+12(0.5x)x-200 = \frac{1}{2}(x) + \frac{1}{2}(0.5x) - x 200=0.5x+0.25xx-200 = 0.5x + 0.25x - x 200=0.25x-200 = -0.25x x=2000.25=800 kJ mol1x = \frac{200}{0.25} = 800 \text{ kJ mol}^{-1} Therefore, the bond dissociation energy of X2X_2 is 800 kJ mol1800 \text{ kJ mol}^{-1}.

Practice Mode Available

Master this Topic on Sushrut

Join thousands of students and practice with AI-generated mock tests.

Get Started