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NEET CHEMISTRYMedium

The half-life of a first-order reaction is 2000 years2000 \text{ years}. If the concentration after 8000 years8000 \text{ years} is 0.02 M0.02 \text{ M}, then the initial concentration was:

A

0.16 M0.16 \text{ M}

B

0.32 M0.32 \text{ M}

C

0.08 M0.08 \text{ M}

D

0.04 M0.04 \text{ M}

Step-by-Step Solution

For a first-order reaction, the number of half-lives is given by n=tt1/2n = \frac{t}{t_{1/2}}. Given total time t=8000 yearst = 8000 \text{ years} and half-life t1/2=2000 yearst_{1/2} = 2000 \text{ years}, the number of half-lives n=80002000=4n = \frac{8000}{2000} = 4. The concentration of the reactant remaining after nn half-lives is given by the formula: [A]=[A]02n[A] = \frac{[A]_0}{2^n} Where: [A]=final concentration=0.02 M[A] = \text{final concentration} = 0.02 \text{ M} [A]0=initial concentration[A]_0 = \text{initial concentration} Substituting the values into the formula: 0.02=[A]0240.02 = \frac{[A]_0}{2^4} 0.02=[A]0160.02 = \frac{[A]_0}{16} [A]0=0.02×16=0.32 M[A]_0 = 0.02 \times 16 = 0.32 \text{ M}. Therefore, the initial concentration was 0.32 M0.32 \text{ M}.

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