At STP, the molar volume of an ideal gas is 22400 mL/mol.
Moles of O2 displaced = 22400 mL/mol5600 mL=0.25 mol.
The half-reaction for the liberation of O2 is:
2H2O→O2+4H++4e−
This shows that 1 mole of O2 gas is produced by the passage of 4 moles of electrons (4 Faradays).
Therefore, the charge (Q) required to displace 0.25 moles of O2=0.25×4=1 Faraday.
The half-reaction for the deposition of silver is:
Ag++e−→Ag
This shows that 1 Faraday of electricity deposits 1 mole of Ag.
Mass of 1 mole of Ag=108 g.
Thus, the weight of silver displaced by 1 Faraday of electricity is 108.0 g.