In acidic medium, changes to which has two (–O – O–) bonds. The oxidation state of in is:
In , the central chromium atom is bonded to one oxygen atom via a double bond (oxide linkage) and four oxygen atoms via single bonds forming two peroxide linkages (–O–O–). Let the oxidation state of be . The oxidation state of oxygen in an oxide linkage is . The oxidation state of oxygen in a peroxide linkage is . So, the sum of oxidation states is: . Thus, the oxidation state of in is .
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