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In acidic medium, H2O2\text{H}_2\text{O}_2 changes Cr2O72\text{Cr}_2\text{O}_7^{2-} to CrO5\text{CrO}_5 which has two (–O – O–) bonds. The oxidation state of Cr\text{Cr} in CrO5\text{CrO}_5 is:

A

+5+5

B

+3+3

C

+6+6

D

10-10

Step-by-Step Solution

In CrO5\text{CrO}_5, the central chromium atom is bonded to one oxygen atom via a double bond (oxide linkage) and four oxygen atoms via single bonds forming two peroxide linkages (–O–O–). Let the oxidation state of Cr\text{Cr} be xx. The oxidation state of oxygen in an oxide linkage is 2-2 . The oxidation state of oxygen in a peroxide linkage is 1-1 . So, the sum of oxidation states is: x+1(2)+4(1)=0    x6=0    x=+6x + 1(-2) + 4(-1) = 0 \implies x - 6 = 0 \implies x = +6. Thus, the oxidation state of Cr\text{Cr} in CrO5\text{CrO}_5 is +6+6.

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