The reason for lanthanoid contraction is:
Negligible screening effect of 'f' orbitals
Increasing nuclear charge
Decreasing nuclear charge
Decreasing screening effect
Lanthanoid contraction is the gradual decrease in the atomic and ionic radii of lanthanoids with an increase in atomic number. As we move along the lanthanoid series, the new electrons are added to the inner subshell. The electrons have a highly diffused shape and provide very poor (negligible) shielding or screening effect. As the nuclear charge increases, the imperfect shielding of the electrons is inadequate to counteract the increased nuclear pull. Consequently, the valence electrons are pulled more strongly towards the nucleus, leading to a contraction in size.
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