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NEET CHEMISTRYEasy

The compound that gives p-cresol with p-methyl diazonium chloride is:

A

H₂O

B

H₃PO₂

C

HCOOH

D

C₆H₅OH

Step-by-Step Solution

To convert a diazonium salt into a phenol, the diazonium group (N2+Cl-N_2^+Cl^-) is replaced by a hydroxyl group (OH-OH). This is achieved by warming the diazonium salt aqueous solution with water (H2OH_2O) or dilute acid.

Reaction: p-CH3C6H4N2+Cl+H2OΔp-CH3C6H4OH (p-Cresol)+N2+HClp\text{-}CH_3-C_6H_4-N_2^+Cl^- + H_2O \xrightarrow{\Delta} p\text{-}CH_3-C_6H_4-OH \text{ (p-Cresol)} + N_2 + HCl

Analysis of other options:

  • H3PO2H_3PO_2 (Hypophosphorous acid): Acts as a reducing agent, replacing the diazonium group with hydrogen (H-H), yielding Toluene.
  • C6H5OHC_6H_5OH (Phenol): Reacts with diazonium salts in a coupling reaction to form azo dyes (e.g., p-hydroxyazobenzene derivative).
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