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NEET CHEMISTRYMedium

Glucose + xx Phenyl hydrazine \rightarrow Osazone. 'xx' will be:

A

2

B

3

C

4

D

1

Step-by-Step Solution

The formation of osazone from glucose requires 3 moles of phenyl hydrazine. The reaction proceeds in three steps:

  1. The first mole of phenyl hydrazine reacts with the aldehyde group (C-1) of glucose to form glucose phenylhydrazone.
  2. The second mole of phenyl hydrazine oxidizes the adjacent secondary alcohol group (at C-2) to a ketonic group. During this process, phenyl hydrazine itself gets reduced to aniline and ammonia.
  3. The third mole of phenyl hydrazine reacts with this newly formed ketonic group at C-2 to yield the final product, glucosazone (osazone). Therefore, x=3x = 3.
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