The complex [Co(en)2Cl2]Cl ionizes to give the coordination entity [Co(en)2Cl2]+. This complex belongs to the type [M(AA)2a2], where 'AA' is a symmetrical bidentate ligand (en) and 'a' is a monodentate ligand (Cl−).
- Geometrical Isomerism: The complex shows geometrical isomerism with two forms:
- Trans-isomer: The two Cl− ions are at 180° to each other. This structure has a plane of symmetry and is optically inactive (achiral).
- Cis-isomer: The two Cl− ions are at 90° to each other. This structure lacks a plane of symmetry and is optically active.
- Optical Isomerism:
- The cis-isomer is chiral and exists as a pair of enantiomers (dextro and laevo forms).
- The trans-isomer is achiral and does not show optical isomerism.
Total Isomers: 1 (Trans) + 2 (Cis-d and Cis-l) = 3 isomers .