Back to Directory
NEET CHEMISTRYEasy

For a cell involving one electron Ecell=0.59 VE^\ominus_{\text{cell}} = 0.59 \text{ V} at 298 K298 \text{ K}. The equilibrium constant for the cell reaction is: [Given that 2.303RTF=0.059 V\frac{2.303 RT}{F} = 0.059 \text{ V} at T=298 KT = 298 \text{ K}]

A

1.0×10301.0 \times 10^{30}

B

1.0×1021.0 \times 10^2

C

1.0×1051.0 \times 10^5

D

1.0×10101.0 \times 10^{10}

Step-by-Step Solution

The relationship between the standard emf of a cell (EcellE^\ominus_{\text{cell}}) and the equilibrium constant (KcK_c) for the cell reaction is given by the Nernst equation at equilibrium:

Ecell=2.303RTnFlogKcE^\ominus_{\text{cell}} = \frac{2.303 RT}{nF} \log K_c

Given: Ecell=0.59 VE^\ominus_{\text{cell}} = 0.59 \text{ V} n=1n = 1 (since the cell involves one electron) 2.303RTF=0.059 V\frac{2.303 RT}{F} = 0.059 \text{ V}

Substituting these values into the equation: 0.59=0.0591logKc0.59 = \frac{0.059}{1} \log K_c logKc=0.590.059=10\log K_c = \frac{0.59}{0.059} = 10

Taking the antilog of both sides: Kc=1010=1.0×1010K_c = 10^{10} = 1.0 \times 10^{10}

Practice Mode Available

Master this Topic on Sushrut

Join thousands of students and practice with AI-generated mock tests.

Get Started