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NEET CHEMISTRYMedium

If the rate of reaction doubles when the temperature is raised from 20C20^\circ\text{C} to 35C35^\circ\text{C}, then the activation energy for the reaction will be : (R=8.314 J mol1 K1R = 8.314 \text{ J mol}^{-1} \text{ K}^{-1})

A

342 kJ mol1342 \text{ kJ mol}^{-1}

B

269 kJ mol1269 \text{ kJ mol}^{-1}

C

34.7 kJ mol134.7 \text{ kJ mol}^{-1}

D

15.1 kJ mol115.1 \text{ kJ mol}^{-1}

Step-by-Step Solution

According to the Arrhenius equation: logk2k1=Ea2.303R[T2T1T1T2]\log \frac{k_2}{k_1} = \frac{E_a}{2.303R} \left[ \frac{T_2 - T_1}{T_1 T_2} \right] Given that the rate doubles, k2=2k1k_2 = 2k_1. T1=20C=20+273=293 KT_1 = 20^\circ\text{C} = 20 + 273 = 293 \text{ K} T2=35C=35+273=308 KT_2 = 35^\circ\text{C} = 35 + 273 = 308 \text{ K} R=8.314 J K1mol1R = 8.314 \text{ J K}^{-1} \text{mol}^{-1} Substituting the values: log(2)=Ea2.303×8.314[308293293×308]\log(2) = \frac{E_a}{2.303 \times 8.314} \left[ \frac{308 - 293}{293 \times 308} \right] 0.3010=Ea19.147[1590244]0.3010 = \frac{E_a}{19.147} \left[ \frac{15}{90244} \right] Ea=0.3010×19.147×9024415E_a = \frac{0.3010 \times 19.147 \times 90244}{15} Ea34673 J mol1E_a \approx 34673 \text{ J mol}^{-1} Ea34.7 kJ mol1E_a \approx 34.7 \text{ kJ mol}^{-1}

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