According to Hess's Law of Constant Heat Summation, if a reaction takes place in several steps, its standard reaction enthalpy is the sum of the standard enthalpies of the intermediate reactions into which the overall reaction may be divided .
By adding the three provided thermochemical equations, we can derive the target equation for the combustion of carbon:
- H2O(g)+C(s)ightarrowCO(g)+H2(g)(ΔH1=131 kJ)
- CO(g)+21O2(g)ightarrowCO2(g)(ΔH2=−282 kJ)
- H2(g)+21O2(g)ightarrowH2O(g)(ΔH3=−242 kJ)
Summing these equations:
(H2O(g)+C(s)+CO(g)+21O2(g)+H2(g)+21O2(g))ightarrow(CO(g)+H2(g)+CO2(g)+H2O(g))
Cancelling common terms on both sides (H2O(g),CO(g),H2(g)) yields the net reaction:
C(s)+O2(g)ightarrowCO2(g)
The total enthalpy change (X) is the sum of the individual enthalpy changes:
X=ΔH1+ΔH2+ΔH3
X=131 kJ+(−282 kJ)+(−242 kJ)
X=131 kJ−524 kJ=−393 kJ.
Thus, the value of X is –393 kJ, matching Option A.