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NEET CHEMISTRYEasy

Based on the following thermochemical equations: (i) H2O(g)+C(s)ightarrowCO(g)+H2(g);ΔH=131 kJH_{2}O(g) + C(s) ightarrow CO(g) + H_{2}(g); \Delta H = 131 \text{ kJ} (ii) CO(g)+12O2(g)ightarrowCO2(g);ΔH=282 kJCO(g) + \frac{1}{2}O_{2}(g) ightarrow CO_{2}(g); \Delta H = -282 \text{ kJ} (iii) H2(g)+12O2(g)ightarrowH2O(g);ΔH=242 kJH_{2}(g) + \frac{1}{2}O_{2}(g) ightarrow H_{2}O(g); \Delta H = -242 \text{ kJ} The value of XX for the reaction C(s)+O2(g)ightarrowCO2(g);ΔH=X kJC(s) + O_{2}(g) ightarrow CO_{2}(g); \Delta H = X \text{ kJ} is [CBSE PMT 1992]:

A

–393 kJ

B

–655 kJ

C

+393 kJ

D

+655 kJ

Step-by-Step Solution

According to Hess's Law of Constant Heat Summation, if a reaction takes place in several steps, its standard reaction enthalpy is the sum of the standard enthalpies of the intermediate reactions into which the overall reaction may be divided .

By adding the three provided thermochemical equations, we can derive the target equation for the combustion of carbon:

  1. H2O(g)+C(s)ightarrowCO(g)+H2(g)(ΔH1=131 kJ)H_{2}O(g) + C(s) ightarrow CO(g) + H_{2}(g) \quad (\Delta H_{1} = 131 \text{ kJ})
  2. CO(g)+12O2(g)ightarrowCO2(g)(ΔH2=282 kJ)CO(g) + \frac{1}{2}O_{2}(g) ightarrow CO_{2}(g) \quad (\Delta H_{2} = -282 \text{ kJ})
  3. H2(g)+12O2(g)ightarrowH2O(g)(ΔH3=242 kJ)H_{2}(g) + \frac{1}{2}O_{2}(g) ightarrow H_{2}O(g) \quad (\Delta H_{3} = -242 \text{ kJ})

Summing these equations: (H2O(g)+C(s)+CO(g)+12O2(g)+H2(g)+12O2(g))ightarrow(CO(g)+H2(g)+CO2(g)+H2O(g))(H_{2}O(g) + C(s) + CO(g) + \frac{1}{2}O_{2}(g) + H_{2}(g) + \frac{1}{2}O_{2}(g)) ightarrow (CO(g) + H_{2}(g) + CO_{2}(g) + H_{2}O(g))

Cancelling common terms on both sides (H2O(g),CO(g),H2(g)H_{2}O(g), CO(g), H_{2}(g)) yields the net reaction: C(s)+O2(g)ightarrowCO2(g)C(s) + O_{2}(g) ightarrow CO_{2}(g)

The total enthalpy change (XX) is the sum of the individual enthalpy changes: X=ΔH1+ΔH2+ΔH3X = \Delta H_{1} + \Delta H_{2} + \Delta H_{3} X=131 kJ+(282 kJ)+(242 kJ)X = 131 \text{ kJ} + (-282 \text{ kJ}) + (-242 \text{ kJ}) X=131 kJ524 kJ=393 kJX = 131 \text{ kJ} - 524 \text{ kJ} = -393 \text{ kJ}.

Thus, the value of XX is –393 kJ, matching Option A.

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