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NEET CHEMISTRYMedium

Which plot of lnk\ln k vs 1/T1/T is consistent with Arrhenius equation?

A

Option 1

B

Option 2

C

Option 3

D

Option 4

Step-by-Step Solution

According to the Arrhenius equation, k=AeEa/RTk = A e^{-E_a/RT}. Taking the natural logarithm on both sides yields: lnk=EaR(1T)+lnA\ln k = -\frac{E_a}{R}\left(\frac{1}{T}\right) + \ln A This equation is of the form y=mx+cy = mx + c, which represents a straight line. Here, y=lnky = \ln k, x=1/Tx = 1/T, slope m=EaRm = -\frac{E_a}{R}, and intercept c=lnAc = \ln A. Since the activation energy EaE_a and the gas constant RR are positive quantities, the slope EaR-\frac{E_a}{R} is negative. Therefore, the plot of lnk\ln k versus 1/T1/T is a straight line with a negative slope.

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